Thermodynamics of diluted ternary sodium amalgams
Identifieur interne : 01BF33 ( Main/Repository ); précédent : 01BF32; suivant : 01BF34Thermodynamics of diluted ternary sodium amalgams
Auteurs : RBID : Pascal:95-0252786Descripteurs français
- Pascal (Inist)
- Propriété thermodynamique, Alliage liquide, Amalgame, Activité thermodynamique, Solution diluée, Alliage ternaire, Méthode électrochimique, Force électromotrice, Etude expérimentale, Sodium alliage, Cadmium alliage, Bismuth alliage, Césium alliage, Indium alliage, Thallium alliage, Mercure alliage, Alliage HgNaTl, Alliage HgInNa, Alliage CdHgNa, Alliage BiHgNa, Aliage CsHgNa, Hg Na Tl, Hg In Na, Cd Hg Na, Bi Hg Na, Cs Hg Na.
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Abstract
Thermodynamic properties of sodium in liquid binary amalgams Tl-Hg, In-Hg, Cd-Hg, Bi-Hg and Cs-Hg have been studied by the emf method. The activity coefficients of sodium for infinitely diluted solutions at 597 K were calculated using experimental data and the lattice models of Blander, and Alcock and Richardson. The existence of the Henry region characteristic of uniformly diluted solution was estimated. A method for the prediction of γNa∞ values for other ternary amalgams having similar properties has been proposed
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<record><TEI><teiHeader><fileDesc><titleStmt><title xml:lang="en" level="a">Thermodynamics of diluted ternary sodium amalgams</title><author><name sortKey="Dergacheva, M B" uniqKey="Dergacheva M">M. B. Dergacheva</name><affiliation wicri:level="1"><inist:fA14 i1="01"><s1>NAN Republic Kazakhstan, inst. organic catalysis electrochemistry</s1><s2>480100 Almaty</s2><s3>KAZ</s3></inist:fA14><country>Kazakhstan</country><placeName><settlement type="city">Almaty</settlement><region nuts="2">Oblys d'Almaty</region></placeName></affiliation></author></titleStmt><publicationStmt><idno type="inist">95-0252786</idno><date when="1995">1995</date><idno type="stanalyst">PASCAL 95-0252786 INIST</idno><idno type="RBID">Pascal:95-0252786</idno><idno type="wicri:Area/Main/Corpus">01CA47</idno><idno type="wicri:Area/Main/Repository">01BF33</idno></publicationStmt><seriesStmt><idno type="ISSN">0044-3093</idno><title level="j" type="abbreviated">Z. Met.kd.</title><title level="j" type="main">Zeitschrift für Metallkunde</title></seriesStmt></fileDesc><profileDesc><textClass><keywords scheme="KwdEn" xml:lang="en"><term>Amalgams</term><term>Bismuth alloy</term><term>Cadmium alloy</term><term>Cesium alloy</term><term>Dilute solution</term><term>Electrochemical method</term><term>Electromotive force</term><term>Experimental study</term><term>Indium alloy</term><term>Liquid alloy</term><term>Mercury alloy</term><term>Sodium alloy</term><term>Ternary alloy</term><term>Thallium alloy</term><term>Thermodynamic activity</term><term>Thermodynamic properties</term></keywords><keywords scheme="Pascal" xml:lang="fr"><term>Propriété thermodynamique</term><term>Alliage liquide</term><term>Amalgame</term><term>Activité thermodynamique</term><term>Solution diluée</term><term>Alliage ternaire</term><term>Méthode électrochimique</term><term>Force électromotrice</term><term>Etude expérimentale</term><term>Sodium alliage</term><term>Cadmium alliage</term><term>Bismuth alliage</term><term>Césium alliage</term><term>Indium alliage</term><term>Thallium alliage</term><term>Mercure alliage</term><term>Alliage HgNaTl</term><term>Alliage HgInNa</term><term>Alliage CdHgNa</term><term>Alliage BiHgNa</term><term>Aliage CsHgNa</term><term>Hg Na Tl</term><term>Hg In Na</term><term>Cd Hg Na</term><term>Bi Hg Na</term><term>Cs Hg Na</term></keywords></textClass></profileDesc></teiHeader><front><div type="abstract" xml:lang="en">Thermodynamic properties of sodium in liquid binary amalgams Tl-Hg, In-Hg, Cd-Hg, Bi-Hg and Cs-Hg have been studied by the emf method. The activity coefficients of sodium for infinitely diluted solutions at 597 K were calculated using experimental data and the lattice models of Blander, and Alcock and Richardson. The existence of the Henry region characteristic of uniformly diluted solution was estimated. A method for the prediction of γ<sub>Na</sub>∞ values for other ternary amalgams having similar properties has been proposed</div></front></TEI><inist><standard h6="B"><pA><fA01 i1="01" i2="1"><s0>0044-3093</s0></fA01><fA02 i1="01"><s0>ZEMTAE</s0></fA02><fA03 i2="1"><s0>Z. Met.kd.</s0></fA03><fA05><s2>86</s2></fA05><fA06><s2>3</s2></fA06><fA08 i1="01" i2="1" l="ENG"><s1>Thermodynamics of diluted ternary sodium amalgams</s1></fA08><fA11 i1="01" i2="1"><s1>DERGACHEVA (M. B.)</s1></fA11><fA14 i1="01"><s1>NAN Republic Kazakhstan, inst. organic catalysis electrochemistry</s1><s2>480100 Almaty</s2><s3>KAZ</s3></fA14><fA20><s1>206-210</s1></fA20><fA21><s1>1995</s1></fA21><fA23 i1="01"><s0>ENG</s0></fA23><fA24 i1="01"><s0>ger</s0></fA24><fA43 i1="01"><s1>INIST</s1><s2>271</s2><s5>354000056108200080</s5></fA43><fA44><s0>0000</s0></fA44><fA45><s0>16 ref.</s0></fA45><fA47 i1="01" i2="1"><s0>95-0252786</s0></fA47><fA60><s1>P</s1></fA60><fA61><s0>A</s0></fA61><fA64 i1="01" i2="1"><s0>Zeitschrift für Metallkunde</s0></fA64><fA66 i1="01"><s0>DEU</s0></fA66><fC01 i1="01" l="ENG"><s0>Thermodynamic properties of sodium in liquid binary amalgams Tl-Hg, In-Hg, Cd-Hg, Bi-Hg and Cs-Hg have been studied by the emf method. The activity coefficients of sodium for infinitely diluted solutions at 597 K were calculated using experimental data and the lattice models of Blander, and Alcock and Richardson. The existence of the Henry region characteristic of uniformly diluted solution was estimated. A method for the prediction of γ<sub>Na</sub>∞ values for other ternary amalgams having similar properties has been proposed</s0></fC01><fC02 i1="01" i2="X"><s0>001C01E02B</s0></fC02><fC02 i1="02" i2="X"><s0>240</s0></fC02><fC03 i1="01" i2="X" l="FRE"><s0>Propriété thermodynamique</s0><s5>01</s5></fC03><fC03 i1="01" i2="X" l="ENG"><s0>Thermodynamic properties</s0><s5>01</s5></fC03><fC03 i1="01" i2="X" l="GER"><s0>Thermodynamische Eigenschaft</s0><s5>01</s5></fC03><fC03 i1="01" i2="X" l="SPA"><s0>Propiedad termodinámica</s0><s5>01</s5></fC03><fC03 i1="02" i2="X" l="FRE"><s0>Alliage liquide</s0><s5>02</s5></fC03><fC03 i1="02" i2="X" l="ENG"><s0>Liquid alloy</s0><s5>02</s5></fC03><fC03 i1="02" i2="X" l="GER"><s0>Fluessige Legierung</s0><s5>02</s5></fC03><fC03 i1="02" i2="X" l="SPA"><s0>Aleación líquida</s0><s5>02</s5></fC03><fC03 i1="03" i2="X" l="FRE"><s0>Amalgame</s0><s2>NA</s2><s5>03</s5></fC03><fC03 i1="03" i2="X" l="ENG"><s0>Amalgams</s0><s2>NA</s2><s5>03</s5></fC03><fC03 i1="03" i2="X" l="GER"><s0>Amalgam</s0><s2>NA</s2><s5>03</s5></fC03><fC03 i1="03" i2="X" l="SPA"><s0>Amalgama</s0><s2>NA</s2><s5>03</s5></fC03><fC03 i1="04" i2="X" l="FRE"><s0>Activité thermodynamique</s0><s5>04</s5></fC03><fC03 i1="04" i2="X" l="ENG"><s0>Thermodynamic activity</s0><s5>04</s5></fC03><fC03 i1="04" i2="X" l="GER"><s0>Thermodynamische Aktivitaet</s0><s5>04</s5></fC03><fC03 i1="04" i2="X" l="SPA"><s0>Actividad termodinámica</s0><s5>04</s5></fC03><fC03 i1="05" i2="X" l="FRE"><s0>Solution diluée</s0><s5>05</s5></fC03><fC03 i1="05" i2="X" l="ENG"><s0>Dilute solution</s0><s5>05</s5></fC03><fC03 i1="05" i2="X" l="SPA"><s0>Solución diluida</s0><s5>05</s5></fC03><fC03 i1="06" i2="X" l="FRE"><s0>Alliage ternaire</s0><s5>06</s5></fC03><fC03 i1="06" i2="X" l="ENG"><s0>Ternary alloy</s0><s5>06</s5></fC03><fC03 i1="06" i2="X" l="SPA"><s0>Aleación ternaria</s0><s5>06</s5></fC03><fC03 i1="07" i2="X" l="FRE"><s0>Méthode électrochimique</s0><s5>07</s5></fC03><fC03 i1="07" i2="X" l="ENG"><s0>Electrochemical method</s0><s5>07</s5></fC03><fC03 i1="07" i2="X" l="SPA"><s0>Método electroquímico</s0><s5>07</s5></fC03><fC03 i1="08" i2="X" l="FRE"><s0>Force électromotrice</s0><s5>08</s5></fC03><fC03 i1="08" i2="X" l="ENG"><s0>Electromotive force</s0><s5>08</s5></fC03><fC03 i1="08" i2="X" l="GER"><s0>Elektromotorische Kraft</s0><s5>08</s5></fC03><fC03 i1="08" i2="X" l="SPA"><s0>Fuerza electromotriz</s0><s5>08</s5></fC03><fC03 i1="09" i2="X" l="FRE"><s0>Etude expérimentale</s0><s5>09</s5></fC03><fC03 i1="09" i2="X" l="ENG"><s0>Experimental study</s0><s5>09</s5></fC03><fC03 i1="09" i2="X" l="GER"><s0>Experimentelle Untersuchung</s0><s5>09</s5></fC03><fC03 i1="09" i2="X" l="SPA"><s0>Estudio experimental</s0><s5>09</s5></fC03><fC03 i1="10" i2="X" l="FRE"><s0>Sodium alliage</s0><s5>10</s5></fC03><fC03 i1="10" i2="X" l="ENG"><s0>Sodium alloy</s0><s5>10</s5></fC03><fC03 i1="10" i2="X" l="GER"><s0>Natriumlegierung</s0><s5>10</s5></fC03><fC03 i1="10" i2="X" l="SPA"><s0>Sodio aleación</s0><s5>10</s5></fC03><fC03 i1="11" i2="X" l="FRE"><s0>Cadmium alliage</s0><s5>11</s5></fC03><fC03 i1="11" i2="X" l="ENG"><s0>Cadmium alloy</s0><s5>11</s5></fC03><fC03 i1="11" i2="X" l="GER"><s0>Cadmiumlegierung</s0><s5>11</s5></fC03><fC03 i1="11" i2="X" l="SPA"><s0>Cadmio aleación</s0><s5>11</s5></fC03><fC03 i1="12" i2="X" l="FRE"><s0>Bismuth alliage</s0><s5>12</s5></fC03><fC03 i1="12" i2="X" l="ENG"><s0>Bismuth alloy</s0><s5>12</s5></fC03><fC03 i1="12" i2="X" l="GER"><s0>Bismutlegierung</s0><s5>12</s5></fC03><fC03 i1="12" i2="X" l="SPA"><s0>Bismuto aleación</s0><s5>12</s5></fC03><fC03 i1="13" i2="X" l="FRE"><s0>Césium alliage</s0><s5>13</s5></fC03><fC03 i1="13" i2="X" l="ENG"><s0>Cesium alloy</s0><s5>13</s5></fC03><fC03 i1="13" i2="X" l="GER"><s0>Caesiumlegierung</s0><s5>13</s5></fC03><fC03 i1="13" i2="X" l="SPA"><s0>Cesio aleación</s0><s5>13</s5></fC03><fC03 i1="14" i2="X" l="FRE"><s0>Indium alliage</s0><s5>14</s5></fC03><fC03 i1="14" i2="X" l="ENG"><s0>Indium alloy</s0><s5>14</s5></fC03><fC03 i1="14" i2="X" l="GER"><s0>Indiumlegierung</s0><s5>14</s5></fC03><fC03 i1="14" i2="X" l="SPA"><s0>Indio aleación</s0><s5>14</s5></fC03><fC03 i1="15" i2="X" l="FRE"><s0>Thallium alliage</s0><s5>23</s5></fC03><fC03 i1="15" i2="X" l="ENG"><s0>Thallium alloy</s0><s5>23</s5></fC03><fC03 i1="15" i2="X" l="GER"><s0>Thalliumlegierung</s0><s5>23</s5></fC03><fC03 i1="15" i2="X" l="SPA"><s0>Talio aleación</s0><s5>23</s5></fC03><fC03 i1="16" i2="X" l="FRE"><s0>Mercure alliage</s0><s5>24</s5></fC03><fC03 i1="16" i2="X" l="ENG"><s0>Mercury alloy</s0><s5>24</s5></fC03><fC03 i1="16" i2="X" l="GER"><s0>Quecksilberlegierung</s0><s5>24</s5></fC03><fC03 i1="16" i2="X" l="SPA"><s0>Mercurio aleación</s0><s5>24</s5></fC03><fC03 i1="17" i2="X" l="FRE"><s0>Alliage HgNaTl</s0><s2>NK</s2><s4>INC</s4><s5>32</s5></fC03><fC03 i1="18" i2="X" l="FRE"><s0>Alliage HgInNa</s0><s2>NK</s2><s4>INC</s4><s5>33</s5></fC03><fC03 i1="19" i2="X" l="FRE"><s0>Alliage CdHgNa</s0><s2>NK</s2><s4>INC</s4><s5>34</s5></fC03><fC03 i1="20" i2="X" l="FRE"><s0>Alliage BiHgNa</s0><s2>NK</s2><s4>INC</s4><s5>35</s5></fC03><fC03 i1="21" i2="X" l="FRE"><s0>Aliage CsHgNa</s0><s2>NK</s2><s4>INC</s4><s5>36</s5></fC03><fC03 i1="22" i2="X" l="FRE"><s0>Hg Na Tl</s0><s4>INC</s4><s5>37</s5></fC03><fC03 i1="23" i2="X" l="FRE"><s0>Hg In Na</s0><s4>INC</s4><s5>38</s5></fC03><fC03 i1="24" i2="X" l="FRE"><s0>Cd Hg Na</s0><s4>INC</s4><s5>39</s5></fC03><fC03 i1="25" i2="X" l="FRE"><s0>Bi Hg Na</s0><s4>INC</s4><s5>40</s5></fC03><fC03 i1="26" i2="X" l="FRE"><s0>Cs Hg Na</s0><s4>INC</s4><s5>41</s5></fC03><fN21><s1>150</s1></fN21></pA></standard></inist></record>Pour manipuler ce document sous Unix (Dilib)
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